22:33a And when the chariot commanders saw that he was not the king of Israel,

That is when the captains/officers of the chariots saw/knew that he was not the king of Israel.
-or-
Then the captains/commanders of the war carts/wagons realized/recognized that he was not the king of Israel

22:33b they turned back from pursuing him.

Then they stopped chasing/attacking him.
-or-
and turned away from him.

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